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Doctoral Thesis
DOI
https://doi.org/10.11606/T.85.2020.tde-06022020-102545
Document
Author
Full name
Caruline de Souza Carvalho Machado
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
São Paulo, 2019
Supervisor
Committee
Costa, Isolda (President)
Abreu, Caio Palumbo de
Lins, Vanessa de Freitas Cunha
Panossian, Zehbour
Title in Portuguese
Estudo da corrosão localizada da liga de alumínio 2198-T8 soldada por fricção e mistura
Keywords in Portuguese
acoplamento galvânico
corrosão localizada
ligas Al-Cu-Li
soldagem por fricção e mistura (FSW)
técnicas eletroquímicas
Abstract in Portuguese
Neste estudo, a microestrutura e a resistência à corrosão da liga AA2198-T8 soldada pelo processo FSW foram investigadas por técnicas microscópicas, ensaios de imersão e eletroquímicos em soluções contendo íons cloreto. Diferentes tipos de corrosão localizada foram observados na liga, os quais foram correlacionados com a microestrutura, principalmente com a presença da fase T1 (Al2CuLi) e de precipitados micrométricos compostos de Al-Cu-Fe. A simulação do perfil térmico, medidas de microdureza, medidas de calorimetria exploratória diferencial e microscopia eletrônica de transmissão foram usadas para estudar a concentração e distribuição da fase T1 ao longo das zonas afetadas pela solda e vizinhanças. Uma correlação inversa entre a microdureza e a resistência à corrosão localizada severa (CLS) foi obtida e relacionada à concentração da fase T1 nas diferentes zonas da liga soldada. A CLS foi predominante na zona não afetada pela solda, ou metal base (MB), quando testada isoladamente ou acoplada galvanicamente às demais zonas. Quando acopladas galvanicamente, a zona de mistura (ZM) atuou como catodo em relação às zonas vizinhas. No entanto, quando esta zona foi testada isoladamente das demais, a CLS foi observada, entretanto, esta foi associada a fase T2/TB. Diferenças na morfologia e cinética de ataque foram observadas entre a ZM e o MB. As técnicas locais mostraram-se apropriadas para o estudo de corrosão dessas ligas, enquanto que as técnicas eletroquímicas convencionais não apresentaram resolução suficiente para diferenciar os tipos de ataque localizado típicos destas ligas.
Title in English
Study of localized corrosion on 2198-T8 aluminum alloy welded by friction stir welding
Keywords in English
Al-Cu-Li alloys
electrochemical techniques
friction stir welding (FSW)
galvanic coupling
localized corrosion
Abstract in English
In this study, the microstructure, the microhardness and the corrosion resistance of the AA2198-T8 alloy welded by the FSW process were investigated by microscopic techniques, immersion tests and electrochemical, global or local, in chloride containing solutions. Different types of localized corrosion were observed in the alloy which were correlated with the microstructure, mainly with the presence of T1 phase (Al2CuLi) and Al-Cu-Fe micrometric precipitates. Thermal profile simulation, microhardness measurements, differential scanning calorimetry measurements and transmission electron microscopy were used to study the concentration and distribution of T1 phase along the zones affected by the weldment and surrounding. An inverse correlation between the microhardness and severe localized corrosion (SLC) resistance was obtained and related to the concentration of the T1 phase in the different zones of the welded alloy. SLC was predominant in the zone not affected by the weldment, or base metal (BM), when tested alone or galvanically coupled to the other zones. When galvanically coupled, the stir zone (SZ) behaves as a cathode in relation to neighboring zones. SLC was observed in the SZ only when this zone was tested in isolation from the others, however, it was associated with T2/TB phases. Differences in morphology and attack kinetics were observed between the SZ and BM. Local techniques proved to be appropriate for the study of corrosion of these alloys, while conventional electrochemical techniques did not present sufficient resolution to differentiate the typical localized attack types of these alloys.
 
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2019MachadoEstudo.pdf (9.80 Mbytes)
Publishing Date
2020-02-07
 
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