• JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
 
  Bookmark and Share
 
 
Master's Dissertation
DOI
https://doi.org/10.11606/D.59.2023.tde-26042023-165316
Document
Author
Full name
Vítor dos Santos de Souza
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
Ribeirão Preto, 2023
Supervisor
Committee
Gonçalves, Rogéria Rocha (President)
Ferrari, Jefferson Luis
Manzani, Danilo
Title in Portuguese
Materiais à base de GeO2 e Nb2O5 dopados com íons terras raras: estudo da emissão de luz branca à luminescência na região do infravermelho
Keywords in Portuguese
Emissão de luz branca
GeO2-Nb2O5
GeO2.9Nb2O5
Luminescência
Temperatura de cor correlacionada
Terras raras
Abstract in Portuguese
O desenvolvimento de novos materiais com emissão de luz branca tem tomado considerado interesse pela comunidade científica, especialmente devido suas diversas aplicações em displays, iluminação interna e externa, e dispositivos optoeletrônicos. Além, da influência que o tipo de branco pode ter no bem-estar do indivíduo e no clico circadiano. Avaliar as propriedades estruturais e espectroscópicas no desenvolvimento de materiais à base de GeO2-Nb2O5 (na proporção de 70Ge:30Nb e 5,3Ge:94,7Nb) dopados com íons terras raras (Ho3+, Yb3+, Tm3+ e Eu3+). Obtidos pela metodologia sol-gel a partir de precursores óxidos e alcóxidos tratados termicamente a 700, 900 e 1100 °C e submetidos a análises de difração de raios X, espectroscopia de absorção na região do infravermelho, análise térmica, microscopia eletrônica de transmissão, reflectância especular, conversão ascendente de energia, espectroscopia M-line e luminescência na região do visível e infravermelho. Nos sistemas nanocompósitos de GeO2-Nb2O5, em proporção 70Ge:30Nb, a obtenção da estrutura GeO2 trigonal é observado em ambas as temperaturas de tratamento, além da estrutural GeO2.9Nb2O5 (GeNb18O47) tetragonal ocorre em altas temperaturas. Resultando em emissão de luz branca fria sob conversão ascendente de energia, e luz branca modulada em função do comprimento de onda de excitação no ultravioleta. Entretanto, na proporção de 5,3Ge:94,7Nb, a estrutura GeO2.9Nb2O5 tetragonal é obtida pura, e o resultados luminescentes demonstram que tal estrutura sozinha não é responsável pela emissão de luz branca. Deste modo, os sistemas de GeO2-Nb2O5 apresentam possível aplicação promissora na iluminação de luz branca, devido à modulação do tipo de branco.
Title in English
Materials based on GeO2 and Nb2O5 doped with rare earth ions: study of white light emission to luminescence in the infrared region
Keywords in English
Correlated color temperature
GeO2-Nb2O5
GeO2.9Nb2O5
Luminescence
Rare earth
White emission
Abstract in English
The development of new materials with white light emission has been of interest to the scientific community. Due to its diverse applications in displays, indoor and outdoor lighting, and optoelectronic devices. In addition, about the influence that the type of white can have on the well-being of the individual, about the circadian cycle. To evaluate the structural and spectroscopic properties in the development of materials based on GeO2-Nb2O5 (in the proportion of 70Ge:30Nb and 5.3Ge:94.7Nb) doped with rare earth ions (Ho3+, Yb3+, Tm3+, and Eu3+). Obtained by the sol-gel methodology from oxide and alkoxide precursors heat treated at 700, 900, and 1100 °C and subjected to X-ray diffraction analysis, absorption spectroscopy in the infrared region, thermal analysis, transmission electron microscopy, reflectance specular, energy upconversion, M-line spectroscopy and luminescence in the visible and infrared region. In nanocomposite systems of GeO2-Nb2O5, in proportion 70Ge:30Nb, obtaining the trigonal GeO2 structure is observed at both treatment temperatures, in addition to the tetragonal GeO2.9Nb2O5 (GeNb18O47) structure occurring at high temperatures. Resulting in the emission of cold white light under energy upconversion, and white light modulated as a function of the excitation wavelength in the ultraviolet. However, in the ratio of 5.3Ge:94.7Nb, the tetragonal GeO2.9Nb2O5 structure is obtained pure, and the luminescent results demonstrate that this structure alone is not responsible for the emission of white light. Thus, the GeO2-Nb2O5 systems present a possible promising application in white light illumination, due to the modulation of the white type.
 
WARNING - Viewing this document is conditioned on your acceptance of the following terms of use:
This document is only for private use for research and teaching activities. Reproduction for commercial use is forbidden. This rights cover the whole data about this document as well as its contents. Any uses or copies of this document in whole or in part must include the author's name.
Publishing Date
2023-04-27
 
WARNING: Learn what derived works are clicking here.
All rights of the thesis/dissertation are from the authors
CeTI-SC/STI
Digital Library of Theses and Dissertations of USP. Copyright © 2001-2024. All rights reserved.