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Master's Dissertation
DOI
https://doi.org/10.11606/D.43.2023.tde-04092023-143205
Document
Author
Full name
Daniel Alves Matos
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
São Paulo, 2023
Supervisor
Committee
Hernandez, Felix Guillermo Gonzalez (President)
Godoy, Marcio Peron Franco de
Peres, Marcelos Lima
Title in Portuguese
Absorção e efeitos da polarização de ondas terahertz no clinocloro.
Keywords in Portuguese
clinocloro
espectroscopia de terahertz no domínio do tempo (THz-TDS)
fônons quirais
radiação terahertz
Abstract in Portuguese
O uso da técnica de THz-TDS tem se mostrado essencial para o estudo das vibrações coletivas da rede cristalina dos sólidos na região do THz. O THz-TDS oferece uma abordagem poderosa ao fornecer informações sobre amplitude e fase do espectro de transmissão. Estudar minerais com a habilidade de serem exfoliados, como o clinocloro, está em destaque por se apresentarem como fontes baratas de materiais bidimensionais. Nesta dissertação, foram exploradas as propriedades do clinocloro na região do THz por meio da técnica THz-TDS. Foi observado um padrão de absorção distintivo em 1,13 THz, o que indica a interação entre o mineral e a radiação THz. Comparando com estudos anteriores, a absorção do clinocloro difere de uma variação sua, a serafinita, provavelmente devido a diferenças nas condições geológicas de formação. Foi constatada também a birrefringência do clinocloro, revelando suas propriedades anisotrópicas e a presença de atividade óptica quiral no clinocloro. Sem a aplicação de um campo magnético externo, a amostra apresentou rotação de Faraday e elipticidade no sinal THz transmitido, indicando sua capacidade de alterar a polarização da luz. Essa característica está relacionada à estrutura cristalina e à presença de impurezas e defeitos, que induzem os fônons a se tornarem circularmente polarizados.
Title in English
Absorption and polarization effects of terahertz waves on clinochlore.
Keywords in English
chiral phonons.
clinochlore
terahertz radiation
terahertz time-domain spectroscopy (THz-TDS)
Abstract in English
The use of THz-TDS technique has proven to be essential for studying the collective vibrations of the crystalline lattice in solids in the THz range. THz-TDS offers a powerful approach by providing information about the amplitude and phase of the transmission spectrum. The study of minerals with the ability to be exfoliated, such as clinochlore, is highlighted as a low-cost source of two-dimensional material. In this dissertation, the properties of clinochlore in the THz region were investigated using the THz-TDS technique. A distinct absorption pattern was observed at 1.13 THz, indicating the interaction between the mineral and THz radiation. Comparisons with previous studies revealed differences in absorption between clinocloro and serafinite, probably due to variations in geological formation conditions. Furthermore, the presence of birrefringence in clinochlore was confirmed, revealing its anisotropic properties and the existence of chiral optical activity. Without the application of an external magnetic field, the sample exhibited Faraday rotation and ellipticity in the transmitted THz signal, indicating its ability to modify the polarization of light. This characteristic is associated with the crystal structure and the presence of impurities and defects that induce circular polarization of phonons.
 
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Publishing Date
2023-10-09
 
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