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Master's Dissertation
DOI
https://doi.org/10.11606/D.11.2021.tde-06102021-154832
Document
Author
Full name
Isabella Rocha Ciarrocchi
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
Piracicaba, 2021
Supervisor
Committee
Spoto, Marta Helena Fillet (President)
Corrêia, Angela de Fátima Kanesaki
Freguglia, Rosana Maria de Oliveira
Maffei, Daniele Fernanda
Title in Portuguese
Efeito da radiação gama na degradação de pesticidas (azoxistrobin e carbendazim) em morango
Keywords in Portuguese
Cromatografia
Descontaminação
Fruta
Fungicidas
Irradiação
Abstract in Portuguese
O excesso de fungicidas pode causar muitos problemas à saúde humana. Portanto, são necessárias medidas para a degradação de resíduos desses fungicidas. No presente estudo, a eficiência da radiação gama (0,5, 1,0, 1,5, 2,0 e 4,0 kGy) na decomposição dos níveis de carbendazim e azoxistrobina em morangos foi monitorada. Amostras de morango irradiadas foram submetidas à extração e quantificação de fungicidas usando o protocolo QuEChERS. A quantificação de carbendazim e azoxistrobina foi realizada por meio de cromatografia líquida de alta eficiência. As doses de radiação de 1,5, 2,0 e 4,0 kGy degradaram 13,17; 15,95 e 27,99% do carbendazim e 25,53; 32,32 e 56,70% da azoxistrobina, respectivamente. A determinação da dose de radiação necessária para diminuir os fungicidas em 50% (RD50) revelou que o carbendazim foi mais resistente do que a azoxistrobina à radiação gama.
Title in English
The effect of radiation gamma in degradation of pesticides (azoxystrobin and carbendazim) in strawberry
Keywords in English
Chromatography
Decontamination
Fruit
Fungicides
Irradiation
Abstract in English
Excess fungicides can trigger many human health problems. Hence, measures for the degradation of fungicide residues are needed. In the present study, the efficiency of gamma radiation (0.5, 1.0, 1.5, 2.0, and 4.0 kGy) in the decomposition of carbendazim and azoxystrobin levels in strawberries was monitored. Irradiated strawberry samples were subjected to extraction and quantification using the QuEChERS protocol. Quantification of carbendazim and azoxystrobin was performed using high-performance liquid chromatography. The radiation doses of 1.5, 2.0, and 4.0 kGy resulted in 13.17, 15.95, and 27.99% of degradation of carbendazim and 25.53, 32.32, and 56.70% of azoxystrobin, respectively. Determination of the radiation dose required to decrease the fungicides by 50% (RD50) revealed that carbendazim was more resistant to gamma radiation than azoxystrobin.
 
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Publishing Date
2021-10-08
 
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