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Doctoral Thesis
DOI
https://doi.org/10.11606/T.88.2013.tde-04062014-094422
Document
Author
Full name
Ester Carvalho de Souza
Institute/School/College
Knowledge Area
Date of Defense
Published
São Carlos, 2013
Supervisor
Committee
Canale, Lauralice de Campos Franceschini (President)
Chinelatto, Marcelo Aparecido
Itman Filho, André
Oliveira, Ana Sofia Climaco Monteiro de
Picon, Carlos Alberto
Title in Portuguese
Comparação do desempenho nas características de resfriamento entre óleos vegetais e minerais
Keywords in Portuguese
Antioxidantes
Coeficiente de transferência de calor
Curvas de resfriamento
Óleos vegetais
Tratamento térmico de têmpera
Abstract in Portuguese
No presente trabalho são relatados os resultados obtidos por meio de ensaios de caracterização para os diferentes tipos de óleos vegetais (algodão, canola, girassol, milho e soja), no estado novo e puro, tais como viscosidade, número de acidez, índice de iodo, índice de saponificação, cromatografia gasosa, curvas de resfriamento e coeficiente de transferência de calor. Esses mesmos ensaios foram realizados também com as amostras de óleo de soja com diferentes concentrações de aditivos antioxidantes. As diferentes formulações feitas com óleo de soja foram submetidas a um processo de envelhecimento acelerado (durante 72 horas), suas propriedades foram comparadas com as de dois óleos minerais utilizados para têmpera. O mesmo foi feito para os óleos vegetais, estes porém foram envelhecidos durante 48 horas. Pode-se então, comparar qual amostra sofreu menor oxidação durante um mesmo tempo de envelhecimento e, desta maneira, avaliar qual aditivo antioxidante obteve melhor desempenho, retardando o processo de oxidação no óleo de soja. Esses estudos também permitiram verificar qual, dentre os óleos vegetais, possui as melhores propriedades para ser utilizado no tratamento térmico de têmpera. Amostras do aço AISI 4140 foram temperadas nos diferentes óleos estudados, obteve-se a curva de dureza e as micrografias óticas para cada amostra temperada.
Title in English
Comparison of the vegetable and mineral oils cooling performance
Keywords in English
Antioxidants
Cooling curves
Heat transfer coefficient
Quenchants to heat treatment
Vegetable oils
Abstract in English
In this work, the results obtained from the characterization of different vegetable oils (cotton, canola, sunflower, corn and soybean) are reported. The oils were evaluated at "new condition" and "pure" by viscosity, acid and iodine number, saponification, gas chromatography, cooling curves and heat transfer coefficient. These same analyses were also performed on samples of soybean oil containing various concentrations of antioxidant. The various formulations prepared with soybean oil were accelerated aged for 72 hours and their properties were compared with two mineral oils used for quenching. Likewise, the vegetable oils were aged for 48 hours long. Therefore, it was possible to identify which sample exhibited the lower oxidation process at the same aging time and, thus, evaluate the antioxidant additive that promoted the improved oxidation performance for soybean oil. Also, these studies allowed verifying which of the vegetable oils had the best properties to be used as quenchants. Samples of AISI 4140 steel were quenched in different oils and the hardness curve and optical microscopy for each sample were obtained.
 
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Publishing Date
2014-06-09
 
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