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Master's Dissertation
DOI
https://doi.org/10.11606/D.85.2007.tde-13062008-154046
Document
Author
Full name
Reinaldo Leonel Caratin
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
São Paulo, 2007
Supervisor
Committee
Araujo, Sumair Gouveia de (President)
Lugão, Ademar Benévolo
Wiebeck, Helio
Title in Portuguese
Estudo da imobilização de rejeitos radioativos em matrizes asfálticas e resíduos elastoméricos utilizando a técnica de microndas
Keywords in Portuguese
betumização
imobilização
microondas
Abstract in Portuguese
No presente trabalho, foi utilizada a técnica de aquecimento por microondas para estudar a imobilização de rejeitos radioativos de nível de atividade baixo e médio, como resinas de troca iônica exauridas, empregadas na remoção de íons indesejáveis dos circuitos primários de refrigeração de reatores nucleares refrigerados a água, e aquelas usadas em colunas de separação química e radionuclídica no controle de qualidade de radioisótopos. Matrizes betuminosas reforçadas com alguns tipos de borrachas (Neoprene®, Silicone e Etileno Vinil Acetato - EVA), provenientes de material descartado ou sobras de produção, foram utilizadas para incorporação dos rejeitos radioativos. As irradiações das amostras foram feitas em um forno de microondas caseiro, que opera com freqüência de 2.450MHz e possui potência de 1.000W. As amostras foram caracterizadas, empregando-se ensaios de penetração, resistência à lixiviação, pontos de amolecimento, fulgor e combustão, termogravimetria e microscopia óptica. Os resultados obtidos mostraram-se compatíveis com os padrões dos componentes das matrizes, indicando que esta técnica é uma alternativa bastante útil aos métodos de imobilização convencionais e para esses tipos de rejeitos radioativos.
Title in English
STUDY OF IMMOBILIZATION OF RADIOACTIVE WASTES IN ASPHALTIC MATRICES AND ELASTOMERIC RESIDUES BY USING MICROWAVE TECHNIQUE
Keywords in English
betumização
microondas imobilização
Abstract in English
In the present work, the technique of microwave heating was used to study the immobilization of low and intermediate activity level radioactive waste, such as spent ion exchange resin used to remove undesirable ions of primary circuits of refrigeration in water refrigerated nuclear reactors, and those used in chemical and radionuclide separation columns in the quality control of radioisotopes. Bitumen matrices reinforced with some kinds of rubber (Neoprene®, silicon and ethylene-vinyl-acetate), from production leftovers or scraps, were used for incorporation of radioactive waste. The samples irradiation was made in a home microwave oven that operates at a frequency of 2.450 MHZ with 1.000W power. The samples were characterized by developing assays on penetration, leaching resistance, softening, flash and combustion points, thermogravimetry and optical microscopy. The obtained results were compatible with the pattern of matrices components, which shows that technique is a very useful alternative to conventional immobilization methods and to those kinds of radioactive waste.
 
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Publishing Date
2009-03-17
 
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