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Master's Dissertation
DOI
https://doi.org/10.11606/D.85.2013.tde-17022014-131803
Document
Author
Full name
Clécia de Moura Souza
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
São Paulo, 2013
Supervisor
Committee
Silva, Leonardo Gondim de Andrade e (President)
Esper, Fábio José
Kodama, Yasko
Title in Portuguese
Utilização da radiação ionizante na reciclagem de pneus inservíveis de automóvel e sua destinação ambiental adequada
Keywords in Portuguese
borracha
degradação
pneus
radiação ionizante
reciclagem
Abstract in Portuguese
O objetivo deste trabalho foi utilizar a radiação ionizante na reciclagem de pneus inservíveis de automóvel. As amostras de borracha de pneus inservíveis foram irradiadas com doses de radiação de 200, 400 e 600kGy, em um acelerador de elétrons. Posteriormente, elas foram caracterizadas por termogravimetria (TG), calorimetria exploratória diferencial (DSC), ensaios mecânicos de tração, espectrofotometria de infravermelho por transformada de Fourier (FTIR) e microscopia eletrônica de varredura (MEV). Por TG foi possível observar os efeitos da radiação na perda de massa do material. Por DSC observou-se as curvas exotérmicas associadas à decomposição e valores de variação de entalpia (ΔH). Foram estudadas as propriedades mecânicas das amostras da matriz elastomérica com o pó de pneu inservível e verificado o seu comportamento frente à radiação ionizante. Os espectros FTIR foram obtidos na região de 4000 650cm-1. Observou-se que não foi possível observar alteração nos picos devido à irradiação. Nos ensaios por MEV as micrografias foram ampliadas de 32 vezes até 1000 vezes e observadas nos tamanhos de 1mm até 20μm. Observou-se nas doses de 200 e 400kGy, rugosidades correspondentes a quebras ou rupturas, possivelmente causadas pela radiação. Na dose de 600kGy, foi possível observar cavidades causadas pela radiação. Observou-se que para todas as doses houve degradação. Para as amostras dos corpos de prova sem pó e com pó de pneus inservíveis com 10%, 30% e 50% de pó as micrografias foram observadas nas ampliações de 100μm e 200μm. Também foi possível observar a incorporação do pó de pneus inservíveis de automóvel na matriz elastomérica das amostras não irradiadas e irradiadas.
Title in English
Use of ionizing radiation in the recycling of unserviceable tires of automotive and its adequate environmental disposal
Keywords in English
degradation
ionizing radiation
recycling
rubber
tires
Abstract in English
The aim of this study was to use ionizing radiation in the recycling of scrap tires of automotive. Samples of rubber unserviceable tires were irradiated with radiation doses 200, 400 and 600kGy in an electron accelerator. Subsequently, they were characterized by thermogravimetry (TG), differential scanning calorimetry (DSC), tensile strenght mechanical test, spectrophotometry Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). By thermogravimetry was possible to observe the effects of radiation in the mass loss of material. In the DSC curves were observed exothermic decomposition peaks and associated values of enthalpy variation (ΔH). The mechanical properties of the elastomeric matrix with unserviceable tires powder were studied and its behavior to ionizing radiation was analyzed. FTIR spectra were obtained in the 4000 - 650cm-1 region. It was observed that there was no change in the peaks due irradiation. For SEM the micrographs were enlarged from 32 times up to 1000 times and observed in sizes from 1mm up to 20μm. It was observed at doses of 200 and 400kGy, roughness corresponding to breaks or ruptures possibly caused by radiation. In 600kGy radiation dose was observed cavities caused by radiation. It was observed that at all doses occurred degradation. For samples without powder and with 10, 30 and 50% of unserviceable tires powder it was obtained micrographs of 100μm and 200μm amplification. Also it was possible to observe the incorporation of unserviceable tires powder of automotive in the elastomeric matrix of non-irradiated and irradiated samples.
 
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Publishing Date
2014-04-07
 
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