• JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
  • JoomlaWorks Simple Image Rotator
 
  Bookmark and Share
 
 
Master's Dissertation
DOI
https://doi.org/10.11606/D.76.2000.tde-07022014-084315
Document
Author
Full name
Fernando Batalioto
Institute/School/College
Knowledge Area
Date of Defense
Published
São Carlos, 2000
Supervisor
Committee
Nunes, Luiz Antonio de Oliveira (President)
Menezes, Jose Carlos Egues de
Pontuschka, Walter Maigon
Title in Portuguese
Caracterização espectroscópica de vidros fluoroindogalato dopados com Nd3+ e com Nd3+ e Yb3+
Keywords in Portuguese
Caracterização espectrocópica
Vidros fluoroindogalato
Abstract in Portuguese
O presente trabalho consiste em uma caracterização ótica de vidros fluoretos dopados com Nd3+ e com Yb3+ dando ênfase ao estudo dos processos de transferência de energia entre estes íons. Também são abordadas possíveis aplicações que os referidos vidros dopados com Nd3+ e codopados com Nd3+ e Yb3+ possam encontrar. Algumas destas aplicações são em meio ativo para laseres no infravermelho e em células solares. Para tal caracterização foram realizadas medidas de absorção, de tempo de vida, de luminescência no infravermelho e no visível e de luminescência resolvida no tempo. Também encontram-se neste trabalho cálculos sobre as probabilidades de transição radiativa dos níveis 4F3/2 do Nd3+ e 2F5/2 do Yb3+ além de um estudo sobre os processos de transferência de energia entre estes íons. Das medidas mencionadas acima foi encontrado que a concentração de neodímio para a qual se observa a emissão mais intensa é de ≅ 1,5% mol Nd F3 e que a eficiência quântica de emissão do nível 4F3/2 deste íon, no vidro fluoroindogalato, é alta (0,96). Nas amostras codopadas com Nd3+ e Yb3+ o máximo da emissão ocorre para a amostra com 1% NdF3 e 2% YbF3. Sobre os processos de transferência de energia, os parâmetros que caracterizam a transferência entre os íons Nd3+ e entre Nd3+ e Yb3+, foram calculados pelo modelo de Dexter e obtidos experimentalmente através das curvas de decaimento da luminescência. Os valores conseguidos das duas maneiras estão em boa concordância entre si
Title in English
Spectroscopy properties of fluoride glasses doped with Nd3+: Yb3+
Keywords in English
Glass
Rare earth
Spectroscopy
Abstract in English
The present work consists in an optical characterization of Nd3+ doped and Nd3+ and Yb3+ codoped fluoride glasses with emphasis on the study of energy transfer processes among these ions. Possible applications that the refered Nd3+ doped and Nd3+ and Yb3+ codoped glasses can find are also considered. Some of these applications are as active media of infrared lasers and in solar cells. The characterization was done by absorption, lifetime, infrared and visible luminescence and time resolved measurements. In this work some calculations of the radioactive transition probabilities of the 4F3/2 do Nd3+ e 2F5/2 of Yb3+ levels and a study of the energy transfer processes among these ions were also carried out. From the above mentioned measurements it was found that the concentration at which the neodymium emission is higher is about 1,5% mol NdF3 and that the quantum efficiency of the emission for the 4F3/2 do Nd3+ of Nd3+ level, in fluoroindogallate, is high (0.96). In the Nd3+ and Yb3+ codoped samples the maximum emission is observed for the sample with 1% Nd3+ and 2% Yb F3. Considering the energy transfer processes, the parameter that characterizes the energy transfer among Nd3+ ions and among Nd3+ and Yb3+ was calculated by Dexter's model and experimentally obtained from the decay curve of the luminescence intensity. The values found are in good agreement to each other
 
WARNING - Viewing this document is conditioned on your acceptance of the following terms of use:
This document is only for private use for research and teaching activities. Reproduction for commercial use is forbidden. This rights cover the whole data about this document as well as its contents. Any uses or copies of this document in whole or in part must include the author's name.
Publishing Date
2014-02-18
 
WARNING: Learn what derived works are clicking here.
All rights of the thesis/dissertation are from the authors
CeTI-SC/STI
Digital Library of Theses and Dissertations of USP. Copyright © 2001-2024. All rights reserved.