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Doctoral Thesis
DOI
https://doi.org/10.11606/T.59.2007.tde-26052009-155131
Document
Author
Full name
Cinara Peverari
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
Ribeirão Preto, 2007
Supervisor
Committee
Serra, Osvaldo Antonio (President)
Pires, Ana Maria
Ribeiro, Sidney José Lima
Rocha Filho, Pedro Alves da
Sigoli, Fernando Aparecido
Title in Portuguese
Compostos de terras raras, com alta absortividade no ultravioleta, como agentes de proteção de radiações solares UV-A e UV-B
Keywords in Portuguese
Cério
Proteção Ultravioleta
Terras raras
UV-A
UV-B
Abstract in Portuguese
A luz do sol possui radiação ultravioleta (UV) que pode ser dividida em luz UVA, com comprimentos de onda na região de 400 a 320 nm; luz UV-B, na região de 320 a 290 nm e luz UV-C para radiações com comprimento de onda menor do que 290 nm, sendo esta última absorvida na atmosfera pelo ozônio. O ser humano dispõe de mecanismos protetores naturais contra as radiações solares, tal como a melanogênese. Entretanto, estes são insuficientes e, por isso, torna-se necessário proteger adequadamente a pele utilizando protetores solares, a fim de minimizar as lesões cutâneas causadas pela radiação solar. Quimicamente, a função dos protetores solares é a absorção da radiação UV, protegendo a pele dos efeitos da exposição à luz solar. Este trabalho visa a preparação de compostos de cério, via método Pechini, com a finalidade de utilizá-los como um componente inorgânico de protetores solares de elevado FPS, juntamente ou substituindo substâncias tais como ZnO e TiO2. A caracterização dos compostos deverá ser realizada por difratometria de raios X, microscopias de eletrônicas de varredura e transmissão, espectroscopia eletrônica de reflectância difusa (ERD) e testes de atividade catalítica e fotocatalítica, pelo método da determinação condutométrica (adaptação RANCIMAT®).
Title in English
Rare earth compounds with high absorptivity in uv as protection agents against UVA and UVB solar radiation
Keywords in English
Cerium
rare earth
ultraviolet protection
UVA
UVB
Abstract in English
Sunlight emits ultraviolet radiation (UV) which is subdivided into three different UV wavelengths: UV-A band in the range of 400-320 nm; UV-B band in the range of 320-290 nm and UV-C band for radiations lesser than 290 nm. The latter is absorbed in the atmospheres ozone layer. Human beings have natural protective mechanisms against solar radiations, such as melanogenys. However, it has been reported that these mechanisms are insufficient to prevent skin damage. Thus, adequate the use of sunscreen (or UV filters) is needed in order to minimize cutaneous injuries caused by solar radiation. Chemically, the function of solar protectors relies on the absorption of UV radiation, which protects the skin from the effect of the exposition to solar light. The present study reports on the synthesis of CeO2-ZnO systems according to Pechini's method. Our objective is to further understand how ZnO modifies the CeO2 nanostructured as we search for a new UV filter material. The characterization of composites will be carried through by X-ray diffraction, transmission electron microscopy (TEM), scanning electron microscopy (SEM), diffuse reflectance spectroscopic and tests of catalytic activity and photocatalytic activity, for the method of the conductometric determination (RANCIMAT adaptation).
 
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CinaraPeverari.pdf (3.09 Mbytes)
Publishing Date
2009-07-13
 
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