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Master's Dissertation
DOI
https://doi.org/10.11606/D.54.1992.tde-14012009-102720
Document
Author
Full name
Haroldo Naoyuki Nagashima
Institute/School/College
Knowledge Area
Date of Defense
Published
São Carlos, 1992
Supervisor
Committee
Faria, Roberto Mendonça (President)
Canevarolo Junior, Sebastião Vicente
Oliveira Junior, Osvaldo Novais de
Title in Portuguese
Migração de carga espacial em copolímeros P(VDF/TrFE)
Keywords in Portuguese
Carga espacial
Copolímero
Materiais poliméricos isolantes
Medida de descarga
Abstract in Portuguese
Este trabalho apresenta um modelo teórico que procura explicar a origem de um pico anômalo de corrente, observado na fase faraeletrica do copolímero P(VDF/TrFE), nos processos de descarga. Quando uma voltagem tipo V(t) = Vo S(t) é aplicado em materiais isolantes, correntes elétricas observadas em medidas, de carga-descarga decaem aproximadamente com T-n e obedecem ao principio da superposição linear (PSL). Esse comportamento e também observado em polímeros dielétricos. Entretanto, nos processos de descarga, acima da temperatura de Curie do copolímero p (VDF/TrFE), surge um pico anomalo de corrente que viola, aparentemente, o (PSL). Apresentamos um modelo de migração de cargas de espaço em presença de armadilhas, que pode ser responsável pelo pico de corrente e que estaria superposta a corrente de descarga da absorção dielétrica, conforme o modelo, durante os processos de carga, impurezas extrínsecas seriam varridas, pelo campo, do volume da amostra e ficariam, preferencialmente, presas em armadilhas de superfície. Nos processos de descarga, essas cargas se deslocariam em direção ao interior da amostra, devido a repulsão Coulombiana. Esse mecanismo de condução gera um pico de corrente. A aplicação do modelo, permitiu-nos inferir valores de parâmetros como a mobilidade dos portadores de carga e o tempo de transito.
Title in English
Space charge migration in P(VDF/TrFE) copolymer
Keywords in English
Copolymer
Discharge measurement
Insulating polymeric materials
Space charge
Abstract in English
A model based on space charge migration to explain an anomalous electric current peak on films of P (VDF/TrFE) copolymer in its paraelectric phase is presented. In general step-voltage current measurements of insulating polymeric materials obey the Principle of Linear Super-position. However, an unexpected anomalous peak was observed in discharge currents in measurements performed with P (VDF/TrFE) above the Curie temperature. We have assumed that space charges were dragged from the bulk of the sample by the external field during the charge measurement, and trapped close to the surface of the sample in a region where the concentration of traps would be very high. Two methods were developed to calculate the magnitude of the current peak: I) assuming a given space charge distribution during the discharge measurement, and II) considering the movement of thin discrete layers of charge under the influence of the internal field.
 
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Publishing Date
2009-01-19
 
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