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Master's Dissertation
DOI
https://doi.org/10.11606/D.3.2006.tde-07122006-173150
Document
Author
Full name
Rui Barbosa de Souza
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
São Paulo, 2006
Supervisor
Committee
John, Vanderley Moacyr (President)
Cincotto, Maria Alba
Kihara, Yushiro
Title in Portuguese
Suscetibilidade de pastas de cimento ao ataque por sulfatos - método de ensaio acelerado.
Keywords in Portuguese
Ataque por sulfatos
DRX
Durabilidade
Método de ensaio
Microestrutura
Sulfato combinado
TG
Abstract in Portuguese
O presente trabalho tem por objetivo investigar e propor uma metodologia rápida e eficaz de avaliação da reatividade do cimento Portland frente ao ataque por sulfatos. O método consiste na utilização de amostras de pasta de cimento hidratada em pó, colocadas em contato direto com soluções concentradas de Na2SO4 e MgSO4, em temperatura elevada (65ºC), para acelerar o ataque. Apesar dos cimentos estudados possuírem composição química parecida, os resultados de SO3 combinado mostraram que o cimento Classe G foi pouco menos suscetível ao ataque por sulfatos em função do maior teor de Fe2O3 presente. Da TG e DRX observou-se a formação de etringita no ataque por ambos os sais de sulfato; e formação de gipsita no ataque por MgSO4. Enquanto havia disponibilidade de portlandita na pasta hidratada, o cimento com adição mineral incorporada apresentou mesma taxa de ataque que os demais (sem adição), entretanto a partir do momento que toda a portlandita foi consumida, iniciou-se um processo de descalcificação do C-S-H, observado pela DRX.
Title in English
Susceptibility of cement pastes to sulfate attack - accelerated test method.
Keywords in English
Combined sulfate
Durability
Microstructure
Sulfate attack
TG
XRD
Abstract in English
The main point of this research is to propose a fast and effective method of evaluation of the cement reactivity to sulfate attack. Resistance to sulfate attack was measured by determining the combined sulfate in cement paste samples with exposure to Na2SO4 and MgSO4 solution, at high temperature (65°C). The samples of cement paste was triturated (powdered) in the proposed method. The results of combined SO3 showed that the Class G cement was little less susceptible to the sulfate attack because it has larger amount of Fe2O3. The ettringite formation was observed in the attack for both sulfate salts; and gypsum formation in the attack for MgSO4 (results of TG and XRD). The blended cement presented same results that the others, however when the Ca(OH)2 was totally consumed, it observed the decalcification of the C-S-H, by XRD.
 
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DissRUIBARBOSA.pdf (3.28 Mbytes)
DissRUIBARBOSAanexoA.pdf (928.57 Kbytes)
DissRUIBARBOSAanexoB.pdf (762.09 Kbytes)
FICHACATALOGRAFICA.doc (25.50 Kbytes)
Publishing Date
2007-08-17
 
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