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Master's Dissertation
DOI
https://doi.org/10.11606/D.18.2006.tde-14092006-222626
Document
Author
Full name
Thiago Ruiz Zimmer
E-mail
Institute/School/College
Knowledge Area
Date of Defense
Published
São Carlos, 2006
Supervisor
Committee
Rodrigues, José Alberto Domingues (President)
Hokka, Carlos Osamu
Zaiat, Marcelo
Title in Portuguese
Influência da carga orgânica e do tempo de enchimento sobre o desempenho do reator anaeróbio em batelada seqüencial com biomassa granulada tratando soro de queijo
Keywords in Portuguese
batelada seqüencial
biomassa granulada
carga orgânica volumétrica
soro de queijo
tempo de enchimento
tratamento anaeróbio
Abstract in Portuguese
Avaliou-se a influência da carga orgânica volumétrica (COV) aplicada e do tempo de enchimento sobre a estabilidade e a eficiência do ASBR com biomassa granulada, operado em batelada e batelada alimentada seqüenciais, tratando soro de queijo diluído. Os ensaios foram realizados a 30 'graus' C com volume total de meio de 5,0 litros e tempo de ciclo de 8 horas. Na primeira etapa realizou-se a operação em batelada com tempo de enchimento ('T IND.alim') de 10 min e freqüência de agitação de 150 rpm. A cada ciclo foram alimentados 2,0 litros de meio com concentração afluente ('C IND.AF') de 1000, 2000, 4000 e 6000 mg/L, em termos de DQO. A suplementação de alcalinidade foi gradualmente otimizada partindo-se da proporção de 1 a 0,25 da razão 'NA'H'CO IND.3'/DQO. Nestas condições foi possível operar o reator com estabilidade a COV aplicada de 4,8 g/L.d , com suplementação de alcalinidade de 25% e eficiência em remoção de matéria orgânica de 96,0% e 98,4% em termos de DQO filtrada e total, respectivamente. Na segunda etapa devido a problemas operacionais desenvolveram-se dispositivos para assegurar a retenção da biomassa a fim de viabilizar a operação em batelada alimentada. Os dispositivos testados foram ASBR híbrido, sistema de agitação com 2 impelidores, hélice e pá-inclinada (a) e hélice e turbina inclinada (b). A solução utilizada foi hélice e turbina inclinada. Para essa configuração, diminuiu-se a freqüência de agitação para 75 rpm e reduziu-se o volume de biomassa para 1,0 L. Dessa forma foi possível avaliar a influência das estratégias de alimentação ('T IND.alim') de 360, 180 e 10 minutos a COV aplicada constante de 2,4 g/L.d, para 'C IND.AF' de 4000 mg/L e 'V IND.alim' de 1,0 L e para 'C IND.AF' de 8000 mg/L e 'V IND.alim' de 0,5 L. Para a 'C IND.AF' de 4000 mg/L o aumento de 'T IND.alim' resultou em diminuição da eficiência, em termos de DQO solúvel, sendo de 97,8 , 96,7 e 94,5% para os 'T IND.alim' de 10, 180 e 360 minutos, respectivamente. Para a 'C IND.AF' de 8000 mg/L o aumento do 'T IND.alim' resultou em menores valores de DQO total no efluente
Title in English
Effect of organic load and fill time on stability and efficiency of an ASBR containing granular biomass treating cheese whey
Keywords in English
anaerobic treatment
cheese whey
fill time
granular biomass
sequencing batch
volumetric organic load
Abstract in English
The effect of volumetric organic load (VOL) and fill time on the stability and efficiency of an ASBR was assessed. The ASBR containing granular biomass was operated in batch and fed-batch mode and treated diluted cheese whey. Assays were performed at 30 'degrees' C with total medium volume of 5.0 liters and 8-h cycle lengths. In a first stage the reactor was operated batch-wise with fill time ('T IND.feed') of 10 min and agitation frequency of 150 rpm. At each cycle 2.0 liters of medium were fed at influent concentration ('C IND.infl') of 1000, 2000, 4000 and 6000 mg/L, in terms of COD. Alkalinity supplementation was gradually optimized from 100% to 25% of 'NA'H'CO IND.3'/COD ratio. At these conditions the reactor attained stability at applied VOL of 4.8 g/L.d, alkalinity supplementation of 25% and organic matter removal efficiency of 96.0% and 98.4% in terms of soluble and total COD, respectively. In a second stage due to operational problems devices were developed to assure biomass retention and hence make fed-batch operation feasible. The tested devices included hybrid ASBR, agitation system with two impellers: helix and inclined blade impeller (a) and helix and inclined turbine impeller (b). The system chosen was the helix and inclined turbine. With this configuration agitation frequency and biomass volume were reduced to 75 rpm and 1.0 L, respectively. This way, it was possible to assess feed strategies ('T IND.feed') of 360, 180 and 10 minutes at constant applied VOL of 2.4 g/L.d, for 'C IND.infl' of 4000 mg/L at 'V IND.feed' of 1.0 L and for 'C IND.infl' of 8000 mg/L at 'V IND.feed' of 0.5 L. At 'C IND.infl' of 4000 mg/L increase in 'T IND.feed' resulted in decrease in efficiency in terms of soluble COD, which amounted to 97.8, 96.7 and 94.5% for 'T IND.feed' of 10, 180 and 360 minutes, respectively. At 'C IND.infl' of 8000 mg/L the increase in 'T IND.feed' resulted in lower values for COD effluent
 
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Publishing Date
2006-09-15
 
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